Ribbon Formation in Twist-Nematic Elastomers
نویسنده
چکیده
Nematic Elastomers (NEs) possess very interesting properties stemming from the interaction between liquid crystal order and rubber elasticity. For such materials, thermally-induced phase transition from the isotropic to the nematic phase may induce very large distortions, which in turn can affect the overall configuration of a macroscopic specimen. The behavior of NEs can be well modeled within the theory of finite elasticity with distortions; here, we test a theoretical model against fancy shapes formation; in particular, we deal with the many different shapes that a thin, slender bar, made of NE, may assume as a consequence of its chiral symmetry during solvent evaporation and subsequent heating. Our goal has been to replicate with numerical experiments the phenomena of shape formation in chiral NEs, and our results constitute a noteworthy assessment of the physical model underlying the numerical solutions.
منابع مشابه
Thermal deformation of imprinted twist nematic elastomers
A nematic elastomer film with a 90 o twist orientation between the top and bottom surfaces is prepared by chiral imprinting methods. The reactive achiral nematic monomers and crosslinkers are photopolymerized in the presence of a controlled amount of unreactive chiral dopant. The elastomer films possess a 90 o twist orientation even after the removal of the chiral dopant. The films exhibit an e...
متن کاملModeling elastic instabilities in nematic elastomers.
Liquid crystal elastomers are cross-linked polymer networks covalently bonded with liquid crystal mesogens. In the nematic phase, due to strong coupling between mechanical strain and orientational order, these materials display strain-induced instabilities associated with formation and evolution of orientational domains. Using a three-dimensional finite element elastodynamics simulation, we inv...
متن کاملStripe–domains in Nematic Elastomers: Old and New
Formation of stripe–domains has often been observed in nematic elastomers, starting from the pioneering work of Finkelmann and coworkers. One of the possible interpretations of this phenomenon is to view it as a material instability driven by energy minimization. This approach, first proposed by Warner and Terentjev, has been quite helpful in the analysis of stretching experiments of thin sheet...
متن کاملShape selection of twist-nematic-elastomer ribbons.
How microscopic chirality is reflected in macroscopic scale to form various chiral shapes, such as straight helicoids and spiral ribbons, and how the degree of macroscopic chirality can be controlled are a focus of studies on the shape formation of many biomaterials and supramolecular systems. This article investigates both experimentally and theoretically how the chiral arrangement of liquid c...
متن کاملPhenomenological theory of isotropic-genesis nematic elastomers.
We consider the impact of the elastomer network on the nematic structure and fluctuations in isotropic-genesis nematic elastomers, via a phenomenological model that underscores the role of network compliance. The model contains a network-mediated nonlocal interaction as well as a new kind of random field that reflects the memory of the nematic order present at network formation and also encodes...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2012